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PROFESSIONAL MOLD INSPECTION INSTITUTE
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Ozone / Hydroxyl Generators - How They Work
What is Ozone?
Ozone is the second most powerful
oxidant in the world, saturates hard-to-reach spaces and leaves no chemical residue, which is why it is useful
for cleaning applications such as mold eradication and odor removal. It also destroys pathogens such as bacteria
and viruses on surfaces making it an excellent disinfectant. Ozone contains three atoms of oxygen rather than the
two in normal air. This extra oxygen atom will quickly combine with or "oxidize" harmful compounds, causing
them to break down. Ozone used in high enough concentrations to kill odors can also damage the respiratory tissues
in humans and animals, and also tissues in plants, requiring it to be used in unoccupied areas only where pets
and plants are removed. Ozone naturally decays back into normal oxygen within a few hours depending on the temperature.
Ultraviolet Light Ozone Generators
There are two ways to make ozone: Ultraviolet Light and Corona Discharge. Both methods occur in nature. Most of
the planet's ozone is generated in the upper stratosphere from high-energy solar radiation (Ultraviolet Light)
breaking apart oxygen molecules which temporarily re-form into groups of 3 (trioxide, a.k.a ozone). Also called
the ozone layer, this gas shields the earth's surface from the sun's most dangerous ultraviolet light and makes
the sky appear blue.
Ultraviolet (UV) Light Ozone
Generators use low pressure UV lamps that generate multiwavelength UV light with two peaks, one at the 254-nm light
band and another at 185-nm. The 185-nm light produces ozone through photolysis of oxygen molecules, while the 254-nm
light photolyzes ozone back into oxygen, which works against the ozone production process. This second peak is
why low pressure UV lamps produce less net ozone (for the energy expended) than corona discharge (CD) ozone generators
when operating in cool, dry environments. However, UV light ozone generators produce ozone at a near constant rate,
even when the environment is warm and wet, making them much better in hot, humid conditions. Plus they do not generate
byproducts from nitrogen in the air.
Ultraviolet Light Ozone Generators can remove strong odors and sterilize viruses and microorganisms under harsh
environmental conditions such as high heat and humidity. The premium ultraviolet light ozone generators that we
sell are innovative, versatile and can generate shock levels of ozone. Our price point averages 50 to 75 percent
lower than similar output ultraviolet ozone generators sold by competitors. Simply put, we sell serious ultraviolet
ozone generators to customers who want high-performing products at the lowest prices. Plus, we stand behind every
product we sell with a money-back guarantee!
Corona
Discharge Ozone Generators
In the lower atmosphere, ozone is generated by static electricity (Corona Discharge) during lightening strikes
which also break apart oxygen molecules that temporarily reform as ozone before reverting back to normal oxygen.
Corona discharge is a static shock that can be generated using electricity. The first man-made ozone machine used
two glass tubes wrapped in tin, one inside of the other so that air could circulate in the space between them.
When the surrounding conductor was energized with high voltage it ionized the air near the conductor surface resulting
in an electrical discharge that produced ozone. Corona discharge is the most efficient way to produce a large volume
of ozone from cool, dry ambient air.
Corona Discharge (CD) Ozone Generators use discharge plates with electrodes and an insulating, dielectric material
that supports an electrostatic field without heating up excessively. A transformer is used to convert standard
low frequency household power into high frequency, high voltage that can produce large quantities of ozone from
the ambient air that passes near the plates. Ozone plate technology and transformer design have improved significantly
over the past few years. Compact, double-sided corona discharge plates can produce 8 to 16 grams of ozone per hour
from a single transformer, allowing a small machine to quickly saturate an area with ozone. However, cool dry air
is required for maximum output, and high humidity can result in undesirable corrosion from nitrogen compounds that
accumulate on the plates. When the environment can be controlled corona discharge ozone generators are the most
efficient choice.
High-output Corona Discharge Ozone Machines remove strong odors and sterilize bacteria, viruses and mold spores
in minutes. The portable ozone generators that we sell are the industry's most powerful and durable units, generating
significantly more ozone than the over-priced "metal box" machines advertised everywhere. Whether it's
for a home, vehicle or a business, when you have serious odor problems you'll want a BoiE to do the job quickly
and completely. Simply put, we sell serious commercial-grade ozone generators to consumers who want high-performing
products that do the job fast at the best price point. Plus, we stand behind every product we sell with a money-back
guarantee and great customer service.
Visit the Line of BoiE Ozone Generators
What
is a Hydroxyl Generator?
Hydroxyls are formed in nature by the reaction of UV light from the sun disassembling water vapor (H20) into hydroxyl
radicals (*OH) which have unpaired electrons. Atmospheric hydroxyl radicals react with and neutralize concentrated
pollutants in outdoor air. However, with an average life of less than a second, natural hydroxyls have little affect
on indoor air. Commercial hydroxyl generators duplicate the effects of outdoor hydroxyl production by circulating
indoor air through a chamber where hydroxyl reactions occur. Hydroxyls start chain reactions with contaminants
that partially break down pollutants with each pass through the machine until all that reamins is carbon dioxide
and water.
Hydroxyl generators are widely used by water and fire damage restoration companies along with mold remediation
professionals because the hydroxyl radicals generated are non-toxic to humans and work exceptionally well in hot,
humid environments to remove the same contaminants as ozone along with many more, although over a longer period
of time. Where a two-hour ozone treatment would be sufficient, a hydroxyl generator might take three times as long
to achieve similar results, but the treatment area can generally remain occupied and the hydroxyls do not cause
damage to sensitive materials such as natural rubber and certain adhesives that concentrated ozone could affect.
Types
of Hydroxyl Generators
There are two methods to generate hydroxyls for indoor air purification: Photocatalytic Oxidation (PCO) or an Advanced
Oxidation Process (AOP). Each method has advantages and disadvantages. PCO is the only method that can be left
running unmonitored in occupied spaces without requiring fresh air ventilation. Contaminants are oxidized by hydroxyls
that form along the surface of a UV light-activated catalyst that abstracts hydrogen atoms from water molecules
in the air.
AOP methods produce hydroxyls from chemical reactions that occur in the air, usually in the presence of UV light
without requiring contact with a catalyst. Also called direct hydroxyl production (DHP), the advantage of AOP is
that more hydroxyls can potentially form because production is not limited to a catalyst surface. The disadvantage
is that byproducts including ozone and hydrogen peroxide may reach harmful levels to humans in some environments,
requiring an area to be unoccupied or closely monitored for occupant or worker safety while machines are running.
PCO was developed with a specific intent not to harm occupants in a closed environment. PCO can use either safe-to-view
UV-A black light or shielded UV-C germicidal light and several types of permanent catalysts. AOP includes low-concentration
ozone and/or hydrogen peroxide vapor that breaks down in the presence of UV-C germicidal light. With either method,
the hydroxyls produced quickly react with VOCs and inorganic gases in cascading reactions that can follow the air
stream outside the generator as partially-oxidized contaminants drive further reactions until they are reduced
to carbon dioxide and water.
Hydroxyl generators are used in the restoration industry in high-humidity environments where ozone is less effective,
especially after floods or fires have been extinguished and materials are very wet. Hydroxyl generators are often
run at the site in the days before serious work starts on a restoration project to help purify the air and prevent
mold from taking hold. Hydroxyl radicals react with over 5,000 compounds and will break apart odors from fire and
smoke, category 2 & 3 water losses, chemical fumes, fuel oil, VOCs, trauma, etc. without damaging sensitive
contents that concentrated ozone might.
Visit the Line of BoiE Hydroxyl Generators
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